What Is Organic Chemistry?: Crash Course Organic Chemistry #1 - By CrashCourse
Transcript
00:0-1 | Hi I'm Debbie Chakravarty and welcome to crash course Organic | |
00:03 | Chemistry . The science of chemistry is pretty incredible because | |
00:06 | it's the science of everything . Stars and computer hard | |
00:10 | drives and desks and our bodies are all made up | |
00:13 | of different arrangements of atoms that are bonded together , | |
00:16 | breaking apart or reacting with each other all the time | |
00:19 | . We already did a crash course about the wonders | |
00:21 | of general chemistry . So this course will focus on | |
00:24 | just a slice of that pie because we're talking about | |
00:27 | organic chemistry and organic chemistry is the study of molecules | |
00:30 | that have carbon atom with four valence electrons . Carbon | |
00:33 | often katyn eights , which means that it bonds to | |
00:36 | itself . So it forms lots of different compounds . | |
00:39 | You can get long chains of carbons and hydrogen is | |
00:41 | like a decade or rings of carbons like anthropocene or | |
00:45 | complex structures with multiple rings and other atoms like the | |
00:48 | steroids , estradiol . You might think that the whole | |
00:50 | focusing on carbon thing would rule out a lot of | |
00:53 | the universe and it does rule out things like glass | |
00:55 | , rocks , minerals and gems other than diamonds . | |
00:58 | But organic chemicals are pretty much everywhere . Over these | |
01:02 | 50 episodes will discover new reactions , new compounds and | |
01:05 | new methods to understand that . And all of these | |
01:07 | discoveries didn't just appear in a chemistry lab notebook overnight | |
01:11 | . They're the result of centuries of hard work isolating | |
01:15 | chemicals trying to figure out what they do and stumbling | |
01:18 | upon happy accidents . That led to revolutionary ideas . | |
01:21 | A big part of understanding organic chemistry is grasping the | |
01:25 | logic behind everything from molecular structures to chemical reaction mechanisms | |
01:30 | . Even though these kinds of problems can feel overwhelming | |
01:32 | , treating them like a puzzle can help us make | |
01:35 | sense of them . So , let's start our story | |
01:36 | with the birth of modern organic chemistry , which begins | |
01:40 | right around the mid 1800s . Film plants like willow | |
01:54 | , ephedra and poppies were known by ancient civilizations to | |
01:57 | have medicinal benefits , but they had no idea why | |
02:01 | . In the early 18 hundreds there was a breakthrough | |
02:03 | in understanding their medicinal properties and people began to extract | |
02:06 | therapeutic chemicals from them . Today , we know these | |
02:09 | plants contain medicinal organic molecules like salicylic acid , ephedrine | |
02:13 | and morphine . Organic means derived from living things . | |
02:17 | And the term organic chemistry was coined by the Swedish | |
02:20 | chemist Yen's Yaka brasilia's , who discovered several elements and | |
02:24 | came up with the modern chemical symbols that we use | |
02:26 | today . At that time , organic chemistry referred to | |
02:29 | the study of chemical compounds extracted from living things . | |
02:32 | We thought that organic compounds could only be harvested from | |
02:35 | living things , but not made . That's why we | |
02:38 | used to dye our fabrics beautiful colors using organic plant | |
02:41 | materials like flowers and dirt . With a little help | |
02:45 | from our own urine . Diarrhea is the main nitrogen | |
02:47 | containing part of urine that comes from our body's metabolic | |
02:50 | breakdown of proteins . But it's also a great fabric | |
02:53 | dyed morden , which is a chemical that makes the | |
02:56 | die last longer and often enhances the color . This | |
02:59 | is because Yuria can form a chemical bridge between the | |
03:02 | dye molecule and the fabric and it shields the die | |
03:05 | from fading . There's evidence that your RIO was used | |
03:07 | by ancient civilizations as a dye additive , particularly for | |
03:11 | indigo dye , the same dye that makes our jeans | |
03:14 | blue in ancient Rome . People would even sell their | |
03:16 | urine to dyer's to make some money . It was | |
03:18 | such a big business that the government even passed a | |
03:21 | urine tax to get a cut of the profits . | |
03:23 | If you've ever tie dye t shirt , the color | |
03:25 | dye solution probably had Yuria in it too . But | |
03:27 | don't worry , since we've moved beyond the get every | |
03:30 | chemical from living things days of organic chemistry , it's | |
03:33 | not derived from your in this area is synthesized from | |
03:36 | an inorganic compound . And for that we can think | |
03:39 | german chemist Friedrich Verlander , he was a rock collector | |
03:43 | and is credited with being the first person to isolate | |
03:45 | the elements atrium , beryllium and titanium . And the | |
03:49 | first person discover organic matter on meteorites . But he's | |
03:52 | most well known for his discovery that an inorganic salt | |
03:55 | , ammonium sion , it could be used to make | |
03:57 | your area without a living organism . Hurlers discovery in | |
04:00 | 1828 is considered the starting point of the modern organic | |
04:03 | chemical industry . And today organic chemistry is defined as | |
04:07 | the study of the structure properties , composition , reactions | |
04:11 | and preparation of carbon containing compounds . This definition includes | |
04:15 | chemicals extracted from living things , but also man made | |
04:18 | polymers like plastic . Throughout this course we need to | |
04:21 | remember this one simple thing . Organic chemistry is carbon | |
04:25 | centric . Carbon is the key atom in all these | |
04:28 | molecules and carbon atoms do some very predictable things . | |
04:31 | Like make four bonds keeping this in mind . There | |
04:34 | are several different ways we can draw organic compounds . | |
04:37 | One way to represent organic molecules is with the LeWIS | |
04:39 | structure , like the ones we drew in crash course | |
04:41 | . General Chemistry LeWIS structures illustrate what atoms are connected | |
04:45 | and they show all the bonds and lone pairs of | |
04:48 | electrons and a molecule for example , propane is a | |
04:51 | common fuel for home heating and barbecue grills . And | |
04:54 | it's a simple organic compounds because we haven't learned how | |
04:56 | to name compounds yet . I'm just going to say | |
04:58 | that pro pains molecular formula is C three H eight | |
05:02 | , so it has three carbon atoms in eight hydrogen | |
05:05 | atoms . Molecular formula tells us the atoms we have | |
05:07 | and how many of each atom there is , but | |
05:10 | it doesn't tell us what's bonded to what for that | |
05:13 | . We'll need a LewiS structure . As I mentioned | |
05:14 | earlier , organic molecules can make carbon chains . So | |
05:17 | let's start by connecting all three of proteins carbons in | |
05:20 | a straight line . Then , knowing that carbon atoms | |
05:23 | prefer to make four bonds , we can add enough | |
05:25 | hydrogen atoms around each carbon so that they have four | |
05:28 | bonds . Lastly , we need to check that we've | |
05:30 | accounted for all three carbons and eight hydrogen and propane | |
05:33 | structure . And more importantly , we need to make | |
05:36 | sure each carbon has eight electrons around it . An | |
05:39 | octet . Remember that each bond represents two electrons . | |
05:42 | So four bonds for carbon is eight electrons . So | |
05:45 | we're good writing Lewis structures for small carbon chains isn't | |
05:48 | too bad . But drawing a bigger organic structure that | |
05:51 | shows all of the bonds hydrogen atoms and electrons can | |
05:55 | start to get complicated and let's be real . Were | |
05:57 | busy chemists , we don't have the time to draw | |
05:59 | every structure like this every time . So the first | |
06:02 | simplification we can make is called a condensed structural formula | |
06:06 | where we group all of the hydrogen together next to | |
06:08 | the carbons they're bonded to instead of drawing each one | |
06:11 | separately . That's better , but it's still a bit | |
06:14 | crowded so we can simplify the structure even more by | |
06:17 | removing all the carbons and they're attached hydrogen . This | |
06:21 | leaves behind a skeleton of lines representing bonds , which | |
06:24 | is why this is called the skeletal formula or line | |
06:27 | angle formula . In skeletal formulas . Carbons are the | |
06:30 | bends or the ends of the lines , and hydrogen | |
06:33 | aren't shown because carbon atoms in most organic compounds have | |
06:37 | four bonds , so the number of hydrogen is needed | |
06:39 | to give each carbon four bonds is implying we can | |
06:42 | take these drawing shortcuts for all kinds of organic molecules | |
06:45 | , no matter how complicated or simple they are , | |
06:48 | for example , let's look at a straight chain of | |
06:50 | eight carbons with the molecular formula C eight h 18 | |
06:53 | . That's octane by the way , but we'll get | |
06:55 | to naming it . In a later video , the | |
06:56 | LewiS structure of octane looks like this . The condensed | |
06:59 | structural formula looks like this and the skeletal formula looks | |
07:03 | like this and you can see that unlike the LewiS | |
07:06 | structure , the skeletal formula uses exact lines to represent | |
07:09 | bonds because we need those bends to see how many | |
07:12 | carbon atoms are in the structure . One long straight | |
07:15 | line basically wouldn't tell us anything . We'll need to | |
07:17 | move between the structural representations a lot throughout this series | |
07:20 | . So , given the skeletal structure for ISO octane | |
07:23 | , an important component in gasoline will need to know | |
07:26 | it translates to this condensed formula and this LewiS structure | |
07:29 | . But the thing is , organic chemistry isn't just | |
07:31 | carbon and hydrogen atoms . We have a whole periodic | |
07:34 | table of elements . We've even got a poster though | |
07:37 | there are a few main ones that are commonly apart | |
07:39 | of organic compounds . These atoms and organic molecules other | |
07:43 | than carbon and hydrogen are called hetero atoms . We | |
07:46 | always show hetero atoms with the attached hydrogen in the | |
07:49 | skeletal formula , like this one for the artificial sweetener | |
07:52 | , aspartame . Also , it's sometimes helpful to show | |
07:55 | the lone pairs of electrons on hetero atoms because it'll | |
07:58 | help us think about chemical reactions . Skeletal formulas make | |
08:01 | it easier for us to focus on the parts of | |
08:03 | an organic structure that are non carbon atoms or have | |
08:06 | double and triple bonds . These parts are called functional | |
08:09 | groups and that's where all the cool chemistry happens . | |
08:11 | We'll be dealing with a lot of these skeletal structures | |
08:13 | or other depictions of organic compounds . But it's also | |
08:17 | important to remember that these chemicals are real things that | |
08:20 | we use on a daily basis ascertain which I just | |
08:22 | mentioned is in the little blue sugar packs that we | |
08:24 | add to our coffee . And this cup is already | |
08:27 | full of organic compounds that give coffee its taste and | |
08:30 | smell , and most importantly , the caffeine that helps | |
08:32 | us wake up in the morning . The whole reason | |
08:34 | anyone can see this video in the first place is | |
08:36 | an organic chemical called retinal , a molecule in our | |
08:39 | eyes that's responsible for turning visible light into nerve signals | |
08:42 | . And not to mention , most video screens and | |
08:45 | computer equipment have lots of organic polymers . One important | |
08:48 | breakthrough in polymer chemistry in the 19 seventies was how | |
08:51 | to make plastics conduct electricity . These special kinds of | |
08:54 | polymers are responsible for lightweight laptops , tablets and phones | |
08:58 | we carry around because plastics are a lot lighter than | |
09:01 | metals . Also , light emitting polymers are responsible for | |
09:04 | full colour displays . These light emitting polymers behave almost | |
09:07 | like metals but change colors with different amounts of electricity | |
09:11 | , plenty of natural things like flowers , fruits and | |
09:13 | vegetables are colored because of organic compounds to like beets | |
09:17 | are high in bed linen , a dye that gives | |
09:19 | them a lovely purple color . Some people don't metabolize | |
09:21 | platinum so it turns their urine and feces purple . | |
09:24 | It's also a great fabric dye . To bring this | |
09:26 | all full circle organic compounds give color to a lot | |
09:29 | of the foods and other things we see every single | |
09:31 | day , whether they're fixed with your area or not | |
09:34 | , I hope you're just as excited as I am | |
09:36 | about how diverse organic compounds are . We're going to | |
09:39 | learn so much together , but in this episode we | |
09:41 | talked about the origins of modern organic chemistry , how | |
09:45 | to write lewis structures , condemned structures and skeletal formulas | |
09:48 | . A brief introduction to functional groups and hetero atoms | |
09:52 | and how romans used to soak their fabrics in urine | |
09:55 | , die to make them pretty colors . Next time | |
09:56 | we'll work on nomenclature and what to call these organic | |
09:59 | molecules . Thanks for watching this episode of Crash Course | |
10:02 | Organic Chemistry . If you want to help keep all | |
10:04 | crash Course free for everybody forever , you can join | |
10:07 | our community on Patreon . Yeah . |
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